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UID:DSC-20406
DTSTART;TZID=Europe/Berlin:20240124T140000
SEQUENCE:1706078405
TRANSP:OPAQUE
DTEND;TZID=Europe/Berlin:20240124T153000
URL:https://www.dresden-science-calendar.de/calendar/en/detail/20406
LOCATION:HZDR\, Bautzner Landstraße 40001328 Dresden
SUMMARY:Tournassat: FWO-Institutskolloquium: „Electrostatic interactions 
 at clay mineral surfaces: At the crossroads between mineralogy\, geochemis
 try\, and geophysics“
CLASS:PUBLIC
DESCRIPTION:Speaker: Christophe Tournassat\nInstitute of Speaker: Professor
  at the University of Orléans\, France\nTopics:\n\n Location:\n  Name: HZ
 DR (L9.3/216 - Bibliothek)\n  Street: Bautzner Landstraße 400\n  City: 01
 328 Dresden\n  Phone: \n  Fax: \nDescription: Electrostatic interactions a
 t clay mineral surfaces: At the crossroads between mineralogy\, geochemist
 ry\, and geophysics Christophe Tournassat (ISTO\, University of Orléans\,
  France\; EESA\, Lawrence Berkeley National Laboratory\, USA)  Clayey mate
 rials properties are key elements in several important subsurface energy-r
 elated applications\, including the long-term disposal of nuclear wastes i
 n geological repositories and the storage of CO2 in subsurface geological 
 formations. Clayey materials show a remarkable array of desirable macro-sc
 ale properties such as very low permeability\, strong adsorption\, semi-pe
 rmeable membrane properties\, and high swelling pressure\, which lead to s
 low advective transport rates\, contaminant retardation\, limited diffusio
 n for anions\, and self-sealing of fractures. These properties arise from 
 the interactions of charged mineral surfaces with water and solutes presen
 t in the nanopores of these materials\, among which electrostatic interact
 ions often play a dominant role.  The study of interactions between water 
 molecules\, ions\, and individual clay mineral surfaces remains an intense
  field of research\, providing a basic understanding to build predictive m
 odels for the simulation of clayey material behavior as a function of phys
 ical and chemical forcing. However\, the behavior of nanoporous clay envir
 onments is complicated by the fact that the pore structure of clay materia
 ls\, but also the surfaces and compositions of clay minerals\, are heterog
 eneous\, and that water and ions can be present in bulk water\, incorporat
 ed within interlayer spaces\, adsorbed to external surfaces\, whether at b
 asal or edge surfaces\, or located within the electrical double layer. Mut
 ual interactions between these system components lead to highly coupled pr
 ocesses and these couplings manifest themselves in macroscopic observation
 s up to geological formation scale\, such as geologic ultrafiltration\, i.
 e. the accumulation of solutes on the inflow side of clay-rich lithologies
 . To understand and predict the coupling phenomena\, a preferred approach 
 is usually built on the following sequence:  i) to examine the physical pr
 ocesses at the molecular and pore scale\, ii) to up-scale the physical law
 s toward the continuum scale\, and iii) to compare continuum scale model p
 redictions to geophysical and geochemical observables. My talk will addres
 s some of the challenges related to this type of upscaling strategy focusi
 ng on the role of electrostatic interactions on clay minerals properties.
DTSTAMP:20260611T212727Z
CREATED:20231222T063815Z
LAST-MODIFIED:20240124T064005Z
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