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UID:DSC-16172
DTSTART;TZID=Europe/Berlin:20190613T150000
SEQUENCE:1561500396
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DTEND;TZID=Europe/Berlin:20190613T163000
URL:https://www.dresden-science-calendar.de/calendar/en/detail/16172
LOCATION:TUD\,    
SUMMARY:Mastalerz: From Soluble Porous Cages to Extended fused π-Systems
CLASS:PUBLIC
DESCRIPTION:Speaker: Prof. Michael Mastalerz\nInstitute of Speaker: Organis
 ch-Chemisches Institut\, Ruprecht-Karls-Universität Heidelberg\, Germany\
 nTopics:\n\n Location:\n  Name: TUD (Bergstr. 66\, 01069\, Dresden - Semin
 ar room CHE 183 (first floor) Chemie-Neubau)\n  Street:   \n  City:  \n  P
 hone: \n  Fax: \nDescription: <span style=\"font-weight: bold\;\"><p>Since
  the introduction of metal-organic frameworks(MOFs)\, porous materials exp
 erienced a real<br>renaissance\, simply because the concept of using oligo
 topic organic linker molecules coordinating to<br>metal ions or metal oxoi
 on clusters allowed to exploit the chemical space by using an infinitesima
 l<br>number of possible organic linker molecules. However\, MOFs as well a
 s the covalent organic<br>frameworks (COFs) and other three-dimensional po
 rous polymers have with zeolites and charcoals<br>in common that these are
  insoluble powders. Shape-persistent molecular organic cages have the<br>a
 dvantage that these are soluble and therefore more easy processable than t
 he above mentioned<br>polymeric compounds. With specific surface areas of 
 up to 3758 m2/g or high selectivities of gas<br>sorption compounds of this
  new type of porous materials are no longer exotic exceptions and can<br>c
 ompete with MOFs\, COFs and zeolites for several applications. The develop
 ment of this field from<br>the perspective of our laboratory is presented.
 <br>Another kind of porous organic molecules are the so called OMIMs (orga
 nic molecules of intrinsic<br>microporosity). These rely on frustrated pac
 king. During our work on OMIMs we entered the field of<br>extended fused 
 π-systems that are highly contorted\, with exciting intrinsic properties.
  These systems<br>are discussed in the second part of the presentation.</p
 ></span><br /></br /><p>Key References<br>Michael Mastalerz\, Porous Shape
 -Persistent Organic Cage Compounds of Different Size\, Geometry and Functi
 on\, Acc. Chem. Res. 2018\, 51\, 2411-2422.<br>Bernd Kohl\, Frank Rominger
 \, Michael Mastalerz*\, A pyrene–fused N-heteroacene with eleven rectili
 nearly annulated aromatic rings characterized by single-crystal X-ray diff
 raction\, Angew. Chem. Int. Ed. 2015\, 54\, 6051-6056</p> <p><strong>BIOGR
 APHY:</strong><br>Since 04/2013 Professor (W3) for Organic Chemistry at Ru
 precht-Karls-Universität Heidelberg<br>02/2013[nbsp][nbsp][nbsp][nbsp][nb
 sp][nbsp][nbsp][nbsp][nbsp] venia legendi<br>2009 – 2013[nbsp][nbsp][nbs
 p][nbsp] Independent Research (equal to Assistant Professor)\, Ulm Univers
 ity/Germany<br>2007 – 2009[nbsp][nbsp][nbsp][nbsp] Post-doc\, Ulm Univer
 sity/Germany\, Supervisor: Prof. Dr. Peter Bäuerle<br>2006 – 2007[nbsp]
 [nbsp][nbsp][nbsp] Post-doc\, Massachusetts Institute of Technology/ Cambr
 idge (USA)\; Supervisor: Prof. Dr. Gregory C. Fu<br>2005 – 2006[nbsp][nb
 sp][nbsp][nbsp] Working at Taros Chemicals GmbH in Dortmund/Germany<br>200
 5[nbsp][nbsp][nbsp][nbsp][nbsp][nbsp][nbsp][nbsp][nbsp][nbsp][nbsp][nbsp][
 nbsp] Ph.D. Thesis at the Ruhr-University of Bochum\; Supervisor: Prof. Dr
 . Gerald Dyker<br>2002[nbsp][nbsp][nbsp][nbsp][nbsp][nbsp][nbsp][nbsp][nbs
 p][nbsp][nbsp][nbsp][nbsp] Diploma Thesis at University Duisburg-Essen\; S
 upervisor: Prof. Dr. Gerald Dyker<br>1997 – 2002[nbsp][nbsp][nbsp][nbsp]
  Studies of Chemistry at Gerhard-Mercator University Duisburg</p> <p><stro
 ng>Main Research Interests</strong></p> <p>- Organic Porous Molecules and 
 Materials by Dynamic Covalent Bond Formation - Crystal Engineering and Sel
 f-Assembling - Supramolecular Chemistry - Nonplanar Extended Aromatic Mole
 cules - Development of New Synthetic Methods</p>
DTSTAMP:20260528T183211Z
CREATED:20190608T220846Z
LAST-MODIFIED:20190625T220636Z
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